NDLI: A New Chiral Route to Optically Pure 3-Oxodicyclopentadiene: A Versatile Chiral Cyclopentadienone Synthon, via Contra-Steric Diels-Alder Reaction

Content Provider	Scilit
Author	Sugahara, Tsutomu Kuroyanagi, Yukari Ogasawara, Kunio
Copyright Year	1996
Description	Optically pure oxodicyclopentadiene (KDP) has been prepared in both enantiomeric forms from racemic 4-tert-butoxycyclopent-2-en-1-one in three ways starting from 4-tert-butoxycyclopent-2-en-1-one involving contra-steric Diels-Alder reaction and lipase-mediated enantiospecific kinetic transesterification as key steps.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1996-4342.pdf
Ending Page	1108
Page Count	8
Starting Page	1101
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1996-4342
Journal	Synthesis
Issue Number	09
Volume Number	1996
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1996-09-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Contra-steric Diels-alder Reaction Lipase-mediated Kinetic Transesterification Chiral Cyclopentadienone Synthon Oxodicyclopentadiene
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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A New Chiral Route to Optically Pure 3-Oxodicyclopentadiene: A Versatile Chiral Cyclopentadienone Synthon, via Contra-Steric Diels-Alder Reaction