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Palladium-Catalyzed Cycloaddition of Alkynes (RC≡CR′) with Dimethylgermylene
| Content Provider | Scilit |
|---|---|
| Author | Brauer, Hartmut Neumann, Wilhelm P. |
| Copyright Year | 1991 |
| Description | The cycloaddition of alkynes with free singlet dimethylgermylene catalyzed by tetrakis(triphenylphosphine)-palladium(0) leads regioselectively in high yield to new 1-germacyclopenta-2,4-dienes, 1,4-digermacyclohexa-2,5-dienes, and 1-oxa-2-germacyclopent-3-enes with an exocyclic double bond. The latter yield, with acetic acid, quantitatively the substituted vinylgermyl acetates. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1991-20753.pdf |
| Ending Page | 432 |
| Page Count | 2 |
| Starting Page | 431 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-1991-20753 |
| Journal | Synlett |
| Issue Number | 06 |
| Volume Number | 1991 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 1991-01-01 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |