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Synthesis of Secondary Allylic Amines
| Content Provider | Scilit |
|---|---|
| Author | Kimpe, Norbert De Stanoeva, Elena Verhé, Roland Schamp, Niceas |
| Copyright Year | 1988 |
| Description | Secondary allylic amines were synthesized from aldehydes and primary amines via successive conversion into aldimines, α-haloaldimines and α,β-unsaturated aldimines, the latter being selectively reduced by sodium borohydride at the imino function. This method allowed the synthesis of secondary allylic amines with high preponderance of the E-stereochemistry. A comparison was made with an alternative method involving the generation of α,β-unsaturated aldimines from α,β-unsaturated aldehydes and primary amines, and subsequent borohydride reduction. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1988-27645.pdf |
| Ending Page | 592 |
| Page Count | 6 |
| Starting Page | 587 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-1988-27645 |
| Journal | Synthesis |
| Issue Number | 08 |
| Volume Number | 1988 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 1988-01-01 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Secondary Allylic Allylic Amines |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
