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Synthesis of Dithiane-Based Photolabile Molecular Systems
| Content Provider | Scilit |
|---|---|
| Author | Kutateladze, Andrei Mitkin, Oleg Wan, Yongqin Kurchan, Alexei |
| Copyright Year | 2001 |
| Description | Synthesis of photolabile molecular systems based on lithiodithiane addition to carbonyl compounds is described. Dithianes of the spiro structure, e. g., 2,4,8,10-tetrathiaspiro[5.5]undecane and 2,4-dithia-8,10-dioxaspiro[5.5]undecane are utilized as tethers, thus allowing for a modular approach to building a diverse set of photocleavable molecules. A variety of carbonyl compounds ranging from simple substituted benzaldehydes to formylated benzocrown ethers, carbohydrates or calixarenes are found to be suitable for this chemistry. |
| Related Links | http://pdfs.semanticscholar.org/2417/097ccade783d3faea5d0767153299b159794.pdf http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2001-15057.pdf |
| Ending Page | 1142 |
| Page Count | 10 |
| Starting Page | 1133 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-2001-15057 |
| Journal | Synthesis |
| Issue Number | 08 |
| Volume Number | 112 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2001-06-21 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Photolabile Molecular Hosts Photoinduced Electron Transfer 10-tetrathiaspiro[5.5]undecane 10-dioxaspiro[5.5]undecane |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
