NDLI: Au-Catalyzed [3+3] Annulation of Azomethine Imines with Propargyl Esters

Content Provider	Scilit
Copyright Year	2009
Description	The authors have reported a gold(III)-catalyzed synthesis of diazabicycles from readily available starting materials. Herein, a formal cycloaddition between alkenyl metal carbenoids and 1,3-dipoles catalyzed by gold dichloride 2-picolinate is reported for the first time. Due to minimization of steric interactions in the aurylated intermediates, the reaction proceeds with high diastereoselectivities.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1218046.pdf
Ending Page	1263
Page Count	1
Starting Page	1263
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0029-1218046
Journal	Synfacts
Issue Number	11
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-10-22
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Formal Cycloaddition Steric Interactions Metal Carbenoids Dipoles Catalyzed Au Catalyzed Azomethine Imines Gold Dichloride Catalyzed Synthesis Starting Materials Propargyl Esters
Content Type	Text
Resource Type	Article

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Au-Catalyzed [3+3] Annulation of Azomethine Imines with Propargyl Esters