NDLI: Palladium Nanoparticles Supported onto Ionic Carbon Nanotubes

Content Provider	Scilit
Editor	Chun, Y. S. Shin, J. Y. Song, C. E. Lee, S. -G
Copyright Year	2008
Description	An aqueous solution of IL-f-MWCNTs 1 and $Na_{2}PdCl_{4}$ was hydrogenated under 1 atm of $H_{2}$ pressure for 30 min at room temperature to give Pd/IL-f-MWCNTs 2a (eq. 1). Direct anion exchange of the hydrophilic Br anion with $NTf_{2}$ and $SbF_{6}$ afforded the hydrophobic Pd/IL-f-MWCNTs 2b and 2c, respectively (eq. 2). The catalytic activities of 2a-c were examined for the hydrogenation of trans-stilbene in MeOH. Pd/IL-f-MWCNT 2c with the $SbF_{6}$ anion showed superior catalytic activity compared to 2a and 2b (eq. 3).
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2008-1072797.pdf
Ending Page	0651
Page Count	1
Starting Page	0651
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-2008-1072797
Journal	Synfacts
Issue Number	06
Volume Number	2008
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2008-05-21
Access Restriction	Open
Subject Keyword	Journal: Synfacts Inorganic Chemistry
Content Type	Text
Resource Type	Synopsis

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