NDLI: Organoaluminum-Promoted Direct Conversion of Aldehydes to the Homologous Ketones or Oxiranes with Diazoalkanes

Content Provider	Scilit
Author	Maruoka, Keiji Concepcion, Arnel B. Yamamoto, Hisashi
Copyright Year	1994
Description	Organoaluminum-promoted single homologation of aliphatic and aromatic aldehydes with diazoalkanes has been described. Among various organoaluminum reagents, exceptionally bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective transformation of aliphatic aldehydes to homologous ketones, while aluminum tris(2,6-diphenylphenoxide) (ATPH) enables the conversion of various aldehydes to oxiranes with diazomethane.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1994-22913.pdf
Ending Page	523
Page Count	3
Starting Page	521
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-1994-22913
Journal	Synlett
Issue Number	07
Volume Number	1994
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1994-01-01
Access Restriction	Open
Subject Keyword	Organic Chemistry Aldehydes To Homologous Ketones
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Organoaluminum-Promoted Direct Conversion of Aldehydes to the Homologous Ketones or Oxiranes with Diazoalkanes