NDLI: Anionic ortho-Fries Rearrangement, a Facile Route to Arenol-Based Mannich Bases

Content Provider	Scilit
Author	Tsoungas, Petros Assimomytis, Nikos Sariyannis, Yiannis Stavropoulos, Georgios Varvounis, George Cordopatis, Paul
Copyright Year	2009
Description	Phenol and 1-naphthol-based carbamates undergo the anionic ortho-Fries rearrangement to their corresponding amides. Bulky substitution at position 8 of 1-naphthol-based carbamates makes the rearrangement an exclusive reaction, even at -90 ˚C, under a variety of conditions. The amides can be efficiently reduced to the corresponding Mannich bases. A novel route to 7-[(dialkylamino)methyl]-8-hydroxy-1-naphthaldehydes is presented.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1217991.pdf
Ending Page	2782
Page Count	6
Starting Page	2777
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0029-1217991
Journal	Synlett
Issue Number	17
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-09-24
Access Restriction	Open
Subject Keyword	Organic Chemistry Ortho-fries Rearrangement
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Anionic ortho-Fries Rearrangement, a Facile Route to Arenol-Based Mannich Bases