NDLI: High Chemoselectivity in the Construction of Aryl Methyl Sulfones via an Unexpected C–S Bond Formation between Sulfonylhydrazides and Dimethyl Phosphite

Content Provider	Scilit
Author	Huang∗, Chao Cheng∗, Feixiang Liu, Teng Yu, Shiwen Shen, Xiang Li, Yixian Liu, Jianjun
Copyright Year	2021
Description	A highly chemoselective route to aryl methyl sulfones via an unexpected C–S bond formation between sulfonylhydrazides and dimethyl phosphite catalyzed by NaI under mild conditions has been established. This transformation provides an alternative and metal-free pathway to acquire various aryl methyl sulfones in good to excellent yields. Notably, dimethyl phosphite was employed as a stable and readily available alkyl source.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1581-2271.pdf
Ending Page	160
Page Count	8
Starting Page	153
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/a-1581-2271
Journal	Synthesis
Issue Number	01
Volume Number	54
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2021-08-09
Access Restriction	Open
Subject Keyword	Journal: Synthesis C–s Bond Formation Dialkyl Phosphites Aryl Methyl Sulfones
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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High Chemoselectivity in the Construction of Aryl Methyl Sulfones via an Unexpected C–S Bond Formation between Sulfonylhydrazides and Dimethyl Phosphite