NDLI: Rh2(OAc)4-Mediated Diazo Decomposition of δ-(N-Tosyl)amino-β-keto-α-diazo Carbonyl Compounds: A Novel Approach to Pyrrole Derivatives

Content Provider	Scilit
Author	Wang, Jianbo Deng, Guisheng Jiang, Nan Ma, Zhihua
Copyright Year	2002
Description	(N-Tosyl)amino substituted β-keto diazo carbonyl compounds have been prepared by reaction of titanium enolate of β-ketodiazoester or -ketone with an activated N-tosylimine. $Rh_{2}(OAc)_{4}$-catalyzed reaction of the (N-tosyl)amino substituted α-diazocarbonyl compounds leads to the efficient formation of pyrrole derivatives.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2002-34888.pdf
Ending Page	1915
Page Count	3
Starting Page	1913
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-2002-34888
Journal	Synlett
Issue Number	11
Volume Number	2002
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2002-10-21
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Diazo Compounds Ti(iv) Enolate Nucleophilic Additions Rh(ii) Carbene
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Rh2(OAc)4-Mediated Diazo Decomposition of δ-(N-Tosyl)amino-β-keto-α-diazo Carbonyl Compounds: A Novel Approach to Pyrrole Derivatives