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Aerobic Palladium-Catalyzed Arylation of Alkenes Using Sodium Sulfinates
| Content Provider | Scilit |
|---|---|
| Author | Taniguchi, Nobukazu |
| Copyright Year | 2013 |
| Description | Palladium-catalyzed oxidative arylations of terminal alkenes could be performed using sodium sulfinates at 60 °C in air. The procedure gave various aryl alkenes after the desulfonylation of sodium arylsulfinates in the presence of a palladium catalyst. For instance, the reaction of styrene with sodium phenylsulfinate afforded trans-1,2-diphenylethylene in 80% yield without the formation of other stereoisomers. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0033-1339846.pdf |
| Ending Page | 2574 |
| Page Count | 4 |
| Starting Page | 2571 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0033-1339846 |
| Journal | Synlett |
| Issue Number | 19 |
| Volume Number | 24 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2013-10-14 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synlett Organic Chemistry Oxidative Arylation Palladium Catalyst Sodium Arylsulfinates Mizoroki–heck Reaction |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |