NDLI: Asymmetric Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

Content Provider	Scilit
Author	Pattison, G. Piraux, G.
Editor	Lam, H. W.
Copyright Year	2010
Description	In this paper the authors report the first catalytic enantioselective addition of arylboronic acids and alkenyl N-methyliminodiacetic acid (MIDA) boronate to β-substituted alkenylheteroarenes. Various types of substrates were employed, containing π-deficient quinoline, quinoxaline, pyrimidine moieties as well as π-excessive oxazole and oxadiazole fragments; the products were obtained in 56-91% yields and with 89-98% ee. Introduction of the alkenyl moiety could be accomplished via alkenyl MIDA boronates. Microwave irradiation could be replaced by thermal heating.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0030-1259108.pdf
Ending Page	0061
Page Count	1
Starting Page	0061
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0030-1259108
Journal	Synfacts
Issue Number	01
Volume Number	2011
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2010-12-21
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Methyliminodiacetic
Content Type	Text
Resource Type	Article

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Asymmetric Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes