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2,4,6-Tris[(4-dichloroiodo)phenoxy)]-1,3,5-triazine as a New Recyclable Hypervalent Iodine(III) Reagent for Chlorination and Oxidation Reactions
| Content Provider | Scilit |
|---|---|
| Author | Karade, Nandkishor N. Thorat, Prerana B. Bhong, Bhagyashree Y. |
| Copyright Year | 2013 |
| Description | The synthesis of 2,4,6-tris[(4-dichloroiodo)phenoxy)]-1,3,5-triazine, as a new recyclable nonpolymeric analogue of (dichloroiodo)benzene, is achieved in two steps using 2,4,6-trichloro-1,3,5-triazine and 4-iodophenol. The application of 2,4,6-tris[(4-dichloroiodo)phenoxy)]-1,3,5-triazine for the chlorination reaction of various activated arenes, olefin, and 1,3-diketone is demonstrated. The reagent 2,4,6-tris[(4-dichloroiodo)phenoxy)]-1,3,5-triazine can be applied also for the oxidative synthesis of 1,3,4-oxadiazoles and 1,2,4-thiadiazoles under mild conditions in excellent yields. The recyclability of the 2,4,6-tris[(4-dichloroiodo)phenoxy)]-1,3,5-triazine was possible owing to the facile recovery and reuse of the coproduced 2,4,6-tris(4-iodophenoxy)-1,3,5-triazine from the reaction mixture due to its practical insolubility in methanol. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0033-1339495.pdf |
| Ending Page | 2066 |
| Page Count | 6 |
| Starting Page | 2061 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0033-1339495 |
| Journal | Synlett |
| Issue Number | 16 |
| Volume Number | 24 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2013-08-14 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry Hypervalent Iodine Reagent (dichloroiodo)benzene |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |
