NDLI: Stereoselective Synthesis of Isoxazolinobenzoxepanes via Intramolecular Nitrile Oxide Cycloaddition

Content Provider	Scilit
Author	Perumal, P. Ramachandiran, K. Karthikeyan, K. Nandhakumar, T. Muralidharan, D.
Copyright Year	2011
Description	Concise routes to the synthesis of indole-tethered nitrile oxides have been developed, and their intramolecular nitrile oxide cycloadditions were studied. Heterocyclic scaffolds involving isoxazolinobenzoxepane frameworks have been achieved via intramolecular nitrile oxide cycloaddition of 3-[1-(2-allyloxyphenyl)-2-nitroethyl]-1H-indole derivatives using $(Boc)_{2}$O and DMAP. This protocol affords products with excellent trans-selectivity.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0030-1260201.pdf
Ending Page	3286
Page Count	10
Starting Page	3277
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0030-1260201
Journal	Synthesis
Issue Number	20
Volume Number	2011
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2011-09-05
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Intramolecular Nitrile Oxide Cycloaddition Isoxazolinobenzoxepanes Trans-selectivity
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Stereoselective Synthesis of Isoxazolinobenzoxepanes via Intramolecular Nitrile Oxide Cycloaddition