Recent Advances in the Asymmetric Hydrosilylation of Ketones, Imines and Electrophilic Double Bonds

Content Provider	Scilit
Author	Riant, Olivier Mostefaï, Naouël Courmarcel, James
Copyright Year	2004
Description	This literature review focuses on the recent advances in the asymmetric hydrosilylation of ketones and imines. New catalyst systems based on various transition metals, such as rhodium, titanium, zinc, copper and tin, combined with classical or new ligand structures, are presented. These systems lead to very effective and selective protocols for the reduction of prochiral ketones, imines and electrophilic double bonds. 1 Introduction 2 Rhodium-Based Catalysts 3 Titanium-Based Catalysts 3.1 Hydrosilylation of Ketones 3.2 Hydrosilylation of Imines 4 Zinc-Based Catalysts 5 Copper-Based catalysts 5.1 Asymmetric Hydrosilylation of Electrophilic Double Bonds 5.2 Asymmetric Hydrosilylation of Ketones and Imines 6 Conclusions
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2004-834932.pdf
Ending Page	2958
Page Count	16
Starting Page	2943
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-2004-834932
Journal	Synthesis
Issue Number	18
Volume Number	2004
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2004-11-24
Access Restriction	Open
Subject Keyword	Journal: Synthesis Inorganic Chemistry Asymmetric Catalysis Asymmetric Hydrosilylation Chiral Ligands Conjugate Addition
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis