NDLI: Asymmetric Synthesis of Chiral Polymers by Means of Repetitive Addition of Allylsilane to Aldehyde

Content Provider	Scilit
Author	Itsuno, Shinichi Kumagai, Toshihiro
Copyright Year	2002
Description	Monomers having both allyltrimethylsilyl and formyl groups were prepared. Chiral (acyloxy)borane initiated the repetitive polyaddition of the monomers to give optically active polymers having main chain configurational chirality. Optical purity of the chiral polymer was evaluated by the analysis of the degradation product.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2002-28502.pdf
Ending Page	944
Page Count	4
Starting Page	941
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-2002-28502
Journal	Synthesis
Issue Number	07
Volume Number	2002
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2002-05-14
Access Restriction	Open
Subject Keyword	Journal: Synthesis Polymer Science Asymmetric Catalysis Asymmetric Polymerization Optically Active Polymers
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Asymmetric Synthesis of Chiral Polymers by Means of Repetitive Addition of Allylsilane to Aldehyde