NDLI: Cyclohexenones via C-C Bond Activation of Allenyl Cyclobutanes

Content Provider	Scilit
Author	Seiser, T. Cramer, N.
Copyright Year	2009
Description	The rhodium(I)-catalyzed synthesis of highly substituted cyclohexanones, with quaternary stereogenic centers, from the corresponding allenyl tert-cyclobutanols is described. The proposed mechanism for this transformation involves enantioselective insertion into the C-C σ-bond of the cyclobutane. In addition, the enantiotopic C-C bond that is activated is reported to be determined by the ligand employed, allowing for access to either of the desired enantiomers.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0028-1087639.pdf
Ending Page	0167
Page Count	1
Starting Page	0167
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0028-1087639
Journal	Synfacts
Issue Number	02
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-01-22
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Em Class Quaternary Stereogenic Transformation Involves Ligand Employed Allenyl Cyclobutanes Highly Substituted
Content Type	Text
Resource Type	Article

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