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Chiral Phosphoric Acid Catalyzed Stereoselective Spiroketalizations
| Content Provider | Scilit |
|---|---|
| Author | Nagorny, Pavel Sun, Zhankui Winschel, Grace A. |
| Copyright Year | 2013 |
| Description | The spiroketal functionality is an important structural motif present in numerous natural products. The synthesis of chiral spiroketals is typically achieved under equilibrating conditions and only few asymmetric approaches are known. We have demonstrated that chiral phosphoric acids (CPAs) could serve as effective catalysts for enantioselective spiroketalizations as well as control the course of the corresponding diastereoselective reactions. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0032-1318098.pdf |
| Ending Page | 665 |
| Page Count | 5 |
| Starting Page | 661 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0032-1318098 |
| Journal | Synlett |
| Issue Number | 06 |
| Volume Number | 24 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2013-01-16 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry Asymmetric Catalysis Enantioselectivity Diastereoselectivity Chiral Phosphoric Acids |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |