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Intramolecular Nitroalkene Diels-Alder Reaction Catalyzed by Brønsted Acids
| Content Provider | Scilit |
|---|---|
| Author | Takenaka, Norito Aguado, Andreina |
| Copyright Year | 2011 |
| Description | Brønsted acid catalysis of intramolecular Diels-Alder cyclizations of (E)-1-nitro-1,6,8-nonatrienes and (E)-1-nitro-1,7,9-decatrienes was investigated. Catalyzed reactions showed significantly higher endo selectivities than the corresponding thermal reactions. To our knowledge, this is the first example of catalysis (substoichiometric amount of catalysts) of the intramolecular nitroalkene Diels-Alder reaction. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0030-1260542.pdf |
| Ending Page | 1261 |
| Page Count | 3 |
| Starting Page | 1259 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0030-1260542 |
| Journal | Synlett |
| Issue Number | 09 |
| Volume Number | 2011 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2011-04-20 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synlett Organic Chemistry Brønsted Acid Catalysis Intramolecular Diels-alder Cyclizations |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |