NDLI: Pyrrolidine-Based Organocatalysts for Enantioselective Michael Addition of Cyclohexanone to trans-β-Nitrostyrene

Content Provider	Scilit
Author	Kilburn, Jeremy D. Carley, Allison P. Dixon, Sally
Copyright Year	2009
Description	A series of readily prepared bifunctional catalysts promote the Michael addition of cyclohexanone to trans-β-nitrostyrene with excellent asymmetric induction. The enantioselection (up to 97%) and diastereoselection (up to 95:5) is comparable to other pyrrolidine-thiourea organocatalysts recently reported, however, reaction times are often shorter.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1216885.pdf
Ending Page	2516
Page Count	8
Starting Page	2509
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0029-1216885
Journal	Synthesis
Issue Number	15
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-07-07
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Addition Reactions Asymmetric Catalysis Michael Additions Bifunctional Catalysis
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Pyrrolidine-Based Organocatalysts for Enantioselective Michael Addition of Cyclohexanone to trans-β-Nitrostyrene