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Oxidative C-Ring Opening of Abietane Diterpenes with Ammonium Cerium(IV) Nitrate
| Content Provider | Scilit |
|---|---|
| Author | Andrés, Lucía Marrero, Joaquín Luis, Javier |
| Copyright Year | 2007 |
| Description | The oxidation reaction of 11,12-di-O-methylcarnosol with ammonium cerium(IV) nitrate (CAN) gave an abietane diterpene with the C-ring opened and a diester function. The structure of this diester was established by spectroscopic analysis and by chemical means. The reaction of 11,12-di-O-dimethylgaldosol with CAN gave a similar result, yielding a δ-lactone which structure was established as 7-hydroxy-11,12-seco-8,13-abietadien-12,7:20,6β-dilacton-11-oic acid methyl ester by spectroscopic analysis and chemical means. These results could be useful to accede to other natural products like rosmic acid. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-977418.pdf |
| Ending Page | 1129 |
| Page Count | 3 |
| Starting Page | 1127 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-2007-977418 |
| Journal | Synlett |
| Issue Number | 7 |
| Volume Number | 2007 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2007-04-13 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synlett Organic Chemistry Abietane Diterpenes Ring Opening Ammonium Cerium(iv) Nitrate |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |
