NDLI: Asymmetric Transfer Hydrogenation in Aqueous Media

Content Provider	Scilit
Author	Kudo, K. Akagawa, K. Akabane, H. Sakamoto, S.
Copyright Year	2008
Description	A highly selective asymmetric transfer hydrogenation of unsaturated aldehydes in aqueous media has been developed. The methodology involves a polyethyleneglycol-polystyrene-supported synthetic peptide catalyst with a terminal proline moiety. Specific characteristics of the catalyst are the hydrophobic polyleucine chain and a β-turn motif at the terminus, providing the specifically high catalytic activity in aqueous media. Products were obtained in yields of 53-76% and enantiomeric ratios of up to 98:2, respectively.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2008-1077817.pdf
Ending Page	0759
Page Count	1
Starting Page	0759
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-2008-1077817
Journal	Synfacts
Issue Number	7
Volume Number	2008
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2008-06-20
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Aqueous Media
Content Type	Text
Resource Type	Article

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Asymmetric Transfer Hydrogenation in Aqueous Media