NDLI: Stereocontrolled Synthesis of Multisubstituted 1,3-Dienes via an Allene

Content Provider	Scilit
Author	Matsumoto, Kenji Shindo, Mitsuru Mizushina, Naoyuki Yoshida, Masahiro
Copyright Year	2017
Description	We herein developed a stereoselective synthetic method for the preparation of multisubstituted 1,3-dienes via an allene–Claisen rearrangement. The Claisen rearrangement of anti-allenyl alcohols provided (1E,3Z)-1,3-dienes, which are essential components of bongkrekic acid, in high stereoselectivities. To demonstrate the synthetic utility of the resulting 1,3-dienes, further functional transformations and Diels–Alder reactions are described.
Related Links	http://pdfs.semanticscholar.org/9779/a797611f833f4f2991ec3248b45ea01a4eef.pdf http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1590970.pdf
Ending Page	2344
Page Count	5
Starting Page	2340
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0036-1590970
Journal	Synlett
Issue Number	17
Volume Number	28
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2017-07-27
Access Restriction	Open
Subject Keyword	Organic Chemistry Claisen Rearrangement Conjugated Dienes Stereoselectivity
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Stereocontrolled Synthesis of Multisubstituted 1,3-Dienes via an Allene–Claisen Rearrangement