NDLI: Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na

Content Provider	Scilit
Author	Li, Yaming Duan, Chunying Yin, Jun Zhang, Rong Jin, Kun
Copyright Year	2013
Description	A copper/silver-catalyzed decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids with $CF_{3}SO_{2}$Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. $Ag_{2}CO_{3}$ plays an important role in promoting the decarboxylation process.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0033-1338578.pdf
Ending Page	612
Page Count	6
Starting Page	607
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0033-1338578
Journal	Synthesis
Issue Number	05
Volume Number	46
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2013-12-17
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Transition Metals
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na