NDLI: Highly Stereoselective Aminohydroxylations ofexo-2-Cyano-7-oxabicyclo[2.2.1]hept-5-en-2-yl Acetate

Content Provider	Scilit
Author	Allemann, Susy Vogel, Pierre
Copyright Year	1991
Description	Protected forms of exo-5-amino-exo-6-hydroxy-7-oxabicyclo [2.2.1]heptan-2-one and of exo-5-amino-endo-6-hydroxy-7-oxabicyclo [2.2.1]heptan-2-one can be obtained readily and with high stereoselectivity from exo-2-cyano-7-oxabicyclo[2.2.1] hept-5-en-2-yl acetate (±)-(7). The processes involve acid promoted rearrangements of N-carbonyl aziridines 10 [(1 RS, 2SR, 4RS,5RS,6SR)-6-cyano-8-oxa-3-azatricyclo[3.2.1.0^{2,4}$] oct-6-yl acetate derivatives] derived from (±)-7.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1991-26607.pdf
Ending Page	928
Page Count	6
Starting Page	923
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1991-26607
Journal	Synthesis
Issue Number	11
Volume Number	1991
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1991-01-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Stereoselectivity
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Highly Stereoselective Aminohydroxylations ofexo-2-Cyano-7-oxabicyclo[2.2.1]hept-5-en-2-yl Acetate