NDLI: Electrophilic Amination: New Synthetic Applications

Content Provider	Scilit
Author	Greck, Christine Genêt, Jean Pierre
Copyright Year	1997
Description	Electrophilic aminating reagents can transfer N-protected group to carbanions or amines. N-Boc and N-Alloc protected amines or hydrazines were easily obtained using metalated t-butyl- or allyl-N-arylsulfonyloxycarbamate. N,O-Bis(trimethylsilyl) hydroxylamine or N-protected oxaziridines were reported to be convenient reagents to give N-protected derivatives. The reaction of β-hydroxy ester enolates with the di-t-butylazodicarboxylate was a convenient entry to α-amino-β-hydroxy acids. Synthetic applications of this reaction are described.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1997-5745.pdf
Ending Page	748
Page Count	8
Starting Page	741
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-1997-5745
Journal	Synlett
Issue Number	7
Volume Number	1997
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1997-07-01
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Α-amino-β-hydroxy Acids Catalytic Hydrogenation Electrophilic Amination N-protected Amines Zinc Enolate
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Electrophilic Amination: New Synthetic Applications