NDLI: Enantioselective Microbial Reduction of Monoesters of 1,3-Dihydroxypropanone: Synthesis of (S)- and (R)-1,2-O-Isopropylideneglycerol

Content Provider	Scilit
Author	Aragozzini, Fabrizio Maconi, Elisabetta Potenza, Donatella Scolastico, Carlo
Copyright Year	1989
Description	The reduction of 3-benzoyloxy-1-hydroxypropanone with bakers' yeast proceeds enantioselectively to afford (S)-3-benzoyloxy-1,2-propanediol, which may be further converted into (S)-(benzoyloxymethyl)oxirane. The bioreduction with fermenting yeast of 1-acetoxy-3-benzyloxypropanone gives (R)-1-benzyloxy-3-acetoxy-2-propanol which can be used for the preparation of both (S)- and (R)-1,2-O-isopropylideneglycerol.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1989-27211.pdf
Ending Page	227
Page Count	3
Starting Page	225
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1989-27211
Journal	Synthesis
Issue Number	03
Volume Number	1989
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1989-01-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Dihydroxypropanone Benzyloxypropanone
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Enantioselective Microbial Reduction of Monoesters of 1,3-Dihydroxypropanone: Synthesis of (S)- and (R)-1,2-O-Isopropylideneglycerol