NDLI: Synthesis of Sugar-Derived Triazole- and Pyridine-Based Metal Complex Ligands

Content Provider	Scilit
Author	Ziegler, Thomas Kraft, Jochen Schmollinger, Daniel Maudrich, Jakob
Copyright Year	2014
Description	A series of 30 bi- and tridentate ligands for metals were prepared by copper-catalyzed coupling (CLICK reaction) of 2-ethynylpridine, 2-ethynyl-5-nitropyridine, 2-ethynylquinoline, and 2,6-diethynylpyridine with 12 protected glycosyl azides in the gluco and galacto series and 2 benzyl azides. The 1,2,3-triazole-linked glycoconjugates prepared were used as ligands for the copper-catalyzed addition of phenylacetylene to N-benzylideneaniline to give chiral N-(1,3-diphenylprop-2-yn-1-yl)aniline.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0034-1379473.pdf
Ending Page	208
Page Count	10
Starting Page	199
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0034-1379473
Journal	Synthesis
Issue Number	02
Volume Number	47
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2014-10-24
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Asymmetric Catalysis Enantioselectivity
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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