NDLI: Aryl-Aryl and Aryl-Alkyl Coupling via N-Heterocycle C-H Activation

Content Provider	Scilit
Copyright Year	2005
Description	The use of heterocyclic N-functionality for anchoring a Pd-catalyst to effect C-H activation at remote but geometrically distinct sites is reported. Thus coupling of alkyl- or aryl-substituted pyridines, methyl-substituted quinolines and condensed systems, as well as pyrazoles with aryl iodines under Pd catalysis in the presence of a Ag(I) source affords arylated products in reasonable yields with modest scope in functionality in the aryl iodine partner. Noteworthy iodo over bromo, i.e. FG = Br, coupling selectivity is observed.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2005-916061.pdf
Ending Page	0209
Page Count	1
Starting Page	0209
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-2005-916061
Journal	Synfacts
Issue Number	02
Volume Number	2005
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2005-10-21
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry
Content Type	Text
Resource Type	Article

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