NDLI: Ruthenium-Catalyzed Synthesis of Phthalides in Water via C-H Alkenylation

Content Provider	Scilit
Author	Ackermann, L. Pospech, J.
Copyright Year	2011
Description	Reported is a concise synthesis of phthalides from benzoic acids and α,β-unsaturated nitriles or esters, involving ruthenium-catalyzed cross-dehydrogenative alkenylation and subsequent intramolecular oxa-Michael reaction. Remarkably, the process is accomplished in water under mild conditions to afford the phthalides in moderate to excellent yields. However, the reaction scope and limitations were not well investigated.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0031-1289278.pdf
Ending Page	1167
Page Count	1
Starting Page	1167
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0031-1289278
Journal	Synfacts
Issue Number	11
Volume Number	2011
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2011-10-19
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry
Content Type	Text
Resource Type	Article

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Ruthenium-Catalyzed Synthesis of Phthalides in Water via C-H Alkenylation