NDLI: Pd-Catalyzed Decarboxylative Arylation of C-H Bonds

Content Provider	Scilit
Copyright Year	2009
Description	An efficient protocol for the ortho-selective C-H arylation using aryl acylperoxides as aryl sources was developed. This decarboxylative arene C-H arylation reaction is supposed to proceed via directing-group-assisted cyclopalladation and subsequent reaction of the resulting palladacycle with the aryl radicals generated in situ from thermal decomposition of the peroxides. Pyridyl, oxime and oxazoline moieties were hereby used as directing groups. Bromo, cyano, aldehyde and nitro groups are well tolerated under the reaction conditions.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1218041.pdf
Ending Page	1265
Page Count	1
Starting Page	1265
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0029-1218041
Journal	Synfacts
Issue Number	11
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-10-22
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Pd-Catalyzed Decarboxylative Arylation of C-H Bonds