NDLI: Dioxygen as Oxidant for the Synthesis of Indoles by Pd-Catalyzed C-H Activation

Content Provider	Scilit
Copyright Year	2009
Description	Jiao and co-workers reported the synthesis of indoles from anilines and alkynes by a C-H activation process catalyzed by $Pd(OAc)_{2}$ which uses dioxygen as the oxidant in the catalytic cycle. The best results were obtained when using a mixture of DMA and pivaloic acid (PivOH) as the solvent. The scope of the reaction was well studied. Thus, both EWGs and EDGs in the starting anilines were well tolerated whereas only electron-deficient alkynes afforded the corresponding indoles in modest to good yields. In addition, N-monosubstituted anilines participated efficiently in the reaction.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1217452.pdf
Ending Page	0846
Page Count	1
Starting Page	0846
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0029-1217452
Journal	Synfacts
Issue Number	08
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-07-23
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry
Content Type	Text
Resource Type	Article

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Dioxygen as Oxidant for the Synthesis of Indoles by Pd-Catalyzed C-H Activation