NDLI: A Facile Synthesis of 1-Chloro-2,2,2-trifluoroethyl Sulfides

Content Provider	Scilit
Author	Pustovit, Yuriy Lukin, Oleg Alexeenko, Anatoliy Trofymchuk, Sergii Tolmachev, Andrey
Copyright Year	2010
Description	A facile synthesis of structurally diverse 1-chloro-2,2,2-trifluoroethyl sulfides from readily available 1-bromo-1-chloro-2,2,2-trifluoroethane $(Halothane^{®}$) and various aliphatic and aromatic thiols in the presence of sodium dithionite/sodium bicarbonate is described. The synthetic utility of the prepared sulfides is illustrated by the synthesis of biologically potent heterocycles and by their electrophilic reactions with thiophene.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1219232.pdf
Ending Page	1165
Page Count	7
Starting Page	1159
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0029-1219232
Journal	Synthesis
Issue Number	07
Volume Number	2010
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2010-01-20
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Radical Reactions Fluorinated Compounds
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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A Facile Synthesis of 1-Chloro-2,2,2-trifluoroethyl Sulfides