NDLI: Catalytic Transfer Hydrogenolysis ofN-Benzyl Protecting Groups

Content Provider	Scilit
Author	O'Farrell, C.
Editor	Adger, B. M. Lewis, N. J. Mitchell, M. B.
Copyright Year	1987
Description	The catalytic transfer hydrogenolysis of a number of N-benzyl compounds has been examined. Of the three hydrogen donors studied, ammonium formate and hydrazine hydrate were more effective than sodium hypophosphite. In general, debenzylation of secondary and tertiary benzylamines could be readily accomplished by refluxing the substrate with an excess of the hydrogen donor in alcoholic solvents for a few hours using catalytic amounts of 10% palladium on carbon. The two N-benzyl heteroaromatic amines studies were stable to the above conditions.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1987-27841.pdf
Ending Page	55
Page Count	3
Starting Page	53
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1987-27841
Journal	Synthesis
Issue Number	01
Volume Number	1987
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1987-01-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Transfer Hydrogenolysis Em Class
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Catalytic Transfer Hydrogenolysis ofN-Benzyl Protecting Groups