NDLI: α-Metallated O-2-Alkenyl Carbamates: Synthetic Equivalents of Chiral Homoenolates and Materials for Asymmetric Homoaldol Reaction

Content Provider	Scilit
Author	Hoppe, Dieter
Copyright Year	2008
Description	The review article provides a personal overview on the development and application in enantioselective synthesis of nonracemic chiral homoenolate reagents, based on allylic N,N-dialkylcarbamates and the ideas behind it. Further, the impact of these results, concerning stereoselective deprotonation, mainly under the influence of the chiral diamine (-)-sparteine, for the generation of a wide range of chiral building blocks is briefly presented.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0028-1083280.pdf
Ending Page	55
Page Count	13
Starting Page	43
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0028-1083280
Journal	Synthesis
Issue Number	01
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2008-12-12
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Stereoselective Deprotonation Chiral Carbanions
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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α-Metallated O-2-Alkenyl Carbamates: Synthetic Equivalents of Chiral Homoenolates and Materials for Asymmetric Homoaldol Reaction