NDLI: Asymmetric Michael Reaction Catalyzed by Chiral Thiophosphoramidate

Content Provider	Scilit
Author	Lu, A. Wu, R. Wang, Y. Zhou, Z. Wu, G. Fang, J. Tang, C.
Copyright Year	2010
Description	The authors report a highly efficient thiophosphoramidate bifunctional catalyst 1a based on the pyrrolidine backbone for the Michael reaction of ketones to nitroolefins. Various nitro-olefins are tolerated with excellent diastereoselectivity and enantioselectivity. Inferior catalytic performance was observed by using an oxo analogue 1b which might be related to its acidity. Review: S. B. Tsogoeva Eur. J. Org. Chem. 2007, 1701-1716.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1219999.pdf
Ending Page	0714
Page Count	1
Starting Page	0714
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0029-1219999
Journal	Synfacts
Issue Number	06
Volume Number	2010
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2010-05-20
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Thiophosphoramidate Enantioselectivity
Content Type	Text
Resource Type	Article

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Asymmetric Michael Reaction Catalyzed by Chiral Thiophosphoramidate