NDLI: Hydrosilylation Catalyzed by the [Silica]-SMAP-Rh System

Content Provider	Scilit
Copyright Year	2007
Description	The compact phosphine 3 was immobilized on silica gel, which was found to be a highly effective ligand for the Rh-catalyzed hydrosilylation of various ketones. TfO-SMAP 2 was prepared via the protodesilylation of 1, and was covalently anchored onto HCl-activated silica gel to give [silica]-SMAP 3. The immobilized phosphine 3 was used as a ligand in the Rh-catalyzed hydrosilylation of ketones 4 where the corresponding silyl ethers 5 were obtained with excellent yields. The Rh-3 catalyst could be recoverd by simple filtration and be reused without loss of catalytic activity.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2007-968959.pdf
Ending Page	1107
Page Count	1
Starting Page	1107
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-2007-968959
Journal	Synfacts
Issue Number	10
Volume Number	2007
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2007-09-19
Access Restriction	Open
Subject Keyword	Journal: Synfacts Organic Chemistry Em Class Catalyzed Hydrosilylation
Content Type	Text
Resource Type	Synopsis

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