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α-Csp3–H Bond Functionalization of Simple Ethers in Radical Reactions
| Content Provider | Scilit |
|---|---|
| Author | Feng, Yanping Ye, Xiajuan Huang, Dayun Guo, Sheng-Rong |
| Copyright Year | 2021 |
| Description | The direct $α-Csp^{3}$–H functionalization of simple ethers is a vital strategy among radical reactions. This review discusses their applications according to the starting materials: (1) reactions with alkenes or alkynes; (2) reactions with other unsaturated compounds; and (3) reactions with nucleophilic partners. Mechanisms like radical addition, C–H activation, elimination, metal-catalyzed coupling, cyclization, oxidation, and rearrangement will be analyzed herein. 1 Introduction 2 Reactions with Alkenes or Alkynes 3 Reactions with Other Unsaturated Compounds 4 Reactions with Nucleophilic Partners 5 Oxidation of Ethers 6 Conclusions Received: 22 July 2021 Accepted after revision: 02 September 2021 Accepted Manuscript online: 02 September 2021 Article published online: 20 October 2021 © 2021. Thieme. All rights reserved Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, Germany |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1631-1606.pdf |
| Ending Page | 333 |
| Page Count | 19 |
| Starting Page | 315 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/a-1631-1606 |
| Journal | Synthesis |
| Issue Number | 02 |
| Volume Number | 54 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2021-09-02 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Csp3–h Bond Functionalization |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |