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Pd(OAc)2/DABCO as a Highly Active Catalytic System for the Heck Reaction
| Content Provider | Scilit |
|---|---|
| Author | Li, Jin-Heng Wang, De-Ping Xie, Ye-Xiang |
| Copyright Year | 2005 |
| Description | The combination of $Pd(OAc)_{2}$ and DABCO (triethylenediamine) was observed as an efficient catalytic system for the Heck cross-coupling reaction. In the presence of $Pd(OAc)_{2}$ and DABCO, a number of ArX (X = I, Br, and Cl) were coupled with olefins efficiently and selectively to afford the corresponding unsymmetric internal olefins in good to excellent yields. Furthermore, the $Pd(OAc)_{2}$/DABCO-catalyzed Heck cross-coupling reaction provided high TONs up to 1,000,000. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2005-869980.pdf |
| Ending Page | 2197 |
| Page Count | 5 |
| Starting Page | 2193 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-2005-869980 |
| Journal | Synthesis |
| Issue Number | 13 |
| Volume Number | 2005 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2005-06-24 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Heck Cross-coupling Reaction |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
