NDLI: Hetero Diels-Alder Reactions with Nitroso Dienophiles: Application to the Synthesis of Natural Product Derivatives

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Hetero Diels-Alder Reactions with Nitroso Dienophiles: Application to the Synthesis of Natural Product Derivatives

Content Provider	Scilit
Author	Streith, Jacques Defoin, Albert
Copyright Year	1994
Description	Hetero Diels-Alder (HDA) reactions with nitroso dienophiles R-N=O are reviewed within the scope of natural product synthesis. These cycloadditions often represent the pivotal reaction step of a total synthesis, because of their high stereo- and regioselective outcome; also because of the introduction of multifunctionality as a direct consequence of the HDA cycloaddition. Asymmetric total syntheses are particularly emphasised using chiral dienes or chiral nitroso dienophiles. 1. Introduction 2. Nitroso Dienophiles 3. Conduramines and Inosamines 4. Pyrrolidine, and Piperidine Alkaloids 5. Indolizidine, and Pyrrolizidine Alkaloids 6. Tropane Alkaloids 7. Tabtoxin and Tabtoxinine-ß-Lactam 8. Antitumor FR 900482 and Mitomycin K 9. Lycoricidine 10. Chiral Amino Acids 11. Conclusion and Outlook
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1994-25647.pdf
Ending Page	1117
Page Count	11
Starting Page	1107
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-1994-25647
Journal	Synthesis
Issue Number	11
Volume Number	1994
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1994-01-01
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Nitroso Dienophiles Diels Alder Natural Product Hetero Diels
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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