NDLI: Mechanistic Insights into Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC): Observation of Asymmetric Amplification

Content Provider	Scilit
Author	Uozumi, Yasuhiro Osako, Takao
Copyright Year	2015
Description	Dedicated to Professor Peter Vollhardt for his peerless contribution to the broad discipline of organic chemistry A mechanistic study of copper-catalyzed azide–alkyne cycloaddition (CuAAC) was examined using an enantioposition-selective asymmetric CuAAC as a probe reaction system. Based on the observed asymmetric amplification (a positive nonlinear effect), we proposed that a dimeric chiral copper complex is involved as a reactive intermediate in the copper-catalyzed azide–alkyne cycloaddition.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0034-1380534.pdf
Ending Page	1479
Page Count	5
Starting Page	1475
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0034-1380534
Journal	Synlett
Issue Number	11
Volume Number	26
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2015-04-02
Access Restriction	Open
Subject Keyword	Journal: Synlett Asymmetric Catalysis Azide–alkyne Cycloaddition Huisgen Reaction Nonlinear Effect
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Mechanistic Insights into Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC): Observation of Asymmetric Amplification