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Enantioselective Rhodium-Catalyzed Alkylative Desymmetrization of 3,5-Dimethylglutaric Anhydride
| Content Provider | Scilit |
|---|---|
| Author | Rovis, Tomislav Cook, Matthew |
| Copyright Year | 2008 |
| Description | A rhodium-catalyzed enantioselective cross-coupling of $sp^{³}$ organozinc reagents and 3,5-dimethylglutaric anhydride has been developed to afford the corresponding products, syn-deoxypolypropionates, in excellent yields and enantioselectivities. This reaction has been developed so that both commercially available and in situ prepared organozinc reagents are competent coupling partners. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0028-1083275.pdf |
| Ending Page | 338 |
| Page Count | 4 |
| Starting Page | 335 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-0028-1083275 |
| Journal | Synthesis |
| Issue Number | 02 |
| Volume Number | 2009 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2008-12-12 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Organozinc Reagents Grignard Reagents C-c Bond Formation Syn-deoxypolypropionates |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |