NDLI: Everything is Falling into Place!

Content Provider	Scilit
Author	Motokuni, K. Okada, T. Takeuchi, D. Osakada, K.
Copyright Year	2011
Description	The Brookhart catalyst system is shown to efficiently catalyze the cyclopolymerization of functionalized trienes. The resulting polymers exclusively exhibit racemo (rather than meso) stereochemistry and display modest tacticity. The authors propose that the high stereoselectivity is a result of the rapid rate of migratory insertion versus the rate of β-hydride elimination during the cyclization process. The post-polymerization hydrolysis of a cyclic acetal functional group is also described, thus permitting access to additional modifications.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0030-1259799.pdf
Ending Page	0501
Page Count	1
Starting Page	0501
ISSN	18611958
e-ISSN	1861194X
DOI	10.1055/s-0030-1259799
Journal	Synfacts
Issue Number	05
Volume Number	2011
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2011-04-15
Access Restriction	Open
Subject Keyword	Journal: Synfacts Stereoselectivity
Content Type	Text
Resource Type	Article

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Everything is Falling into Place!