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Use of 1,2,4-Triazolyl-1,2,3-Triazoles as Carbene Precursors
| Content Provider | Scilit |
|---|---|
| Author | Zibinsky, M. Fokin, V. |
| Copyright Year | 2011 |
| Description | Diazo compounds are excellent precursors for the generation of reactive metal carbenoid species. The authors demonstrate that triazoles bearing an electron-withdrawing heterocycle at the 1-position can serve as carbene precursors, which can subsequently undergo highly enantioselective cyclopropanation reactions or transannulations with nitriles. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0031-1289209.pdf |
| Ending Page | 1215 |
| Page Count | 1 |
| Starting Page | 1215 |
| ISSN | 18611958 |
| e-ISSN | 1861194X |
| DOI | 10.1055/s-0031-1289209 |
| Journal | Synfacts |
| Issue Number | 11 |
| Volume Number | 2011 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2011-10-19 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synfacts Organic Chemistry |
| Content Type | Text |
| Resource Type | Article |