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Iron-Catalyzed Intramolecular Alkyne–Carbonyl Metathesis: A New Cyclization Strategy for the Synthesis of Benzocarbazole and Azepino[1,2-a]indole Derivatives
| Content Provider | Scilit |
|---|---|
| Author | Jana, Umasish Paul, Kartick Jalal, Swapnadeep Kundal, Sandip Chakraborty, Baitan |
| Copyright Year | 2017 |
| Description | Published as part of the Special Topic Modern Cyclization Strategies in Synthesis An efficient synthesis of benzocarbazoles and benzo[3,4]azepino[1,2-a]indole derivatives through an $FeCl_{3}$-catalyzed alkyne–aldehyde metathesis reaction is described. Structurally diverse benzo[a]carbazoles, benzo[c]carbazoles, and benzo[3,4]azepino[1,2-a]indoles have been achieved in good yields with high regio- and chemoselectivity in the presence of catalytic, inexpensive, and environmentally friendly $FeCl_{3}$ as a catalyst. |
| Related Links | http://pdfs.semanticscholar.org/cf93/3bb9e8076d0a93e824465b93dbdd2ab6f28f.pdf http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1588472.pdf |
| Ending Page | 4212 |
| Page Count | 8 |
| Starting Page | 4205 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-0036-1588472 |
| Journal | Synthesis |
| Issue Number | 18 |
| Volume Number | 49 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2017-07-20 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Organic Chemistry Fused-ring Systems Homogeneous Catalysis Lewis Acids |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
