NDLI: Synthesis of Onychine and Formal Synthesis of Eupolauridine via the Vinylogous Aza-Morita-Baylis-Hillman Reaction

Content Provider	Scilit
Author	Back, Thomas Clary, Kristen
Copyright Year	2010
Description	A concise and efficient synthesis of the antimycotic alkaloid onychine was developed, based on the vinylogous aza-Morita-Baylis-Hillman reaction of N-(benzylidene)benzenesulfonamide with methyl 2,4-pentadienoate, followed by intramolecular conjugate addition, Friedel-Crafts acylation, methyl cuprate addition, and aromatization.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0030-1259008.pdf
Ending Page	2804
Page Count	3
Starting Page	2802
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0030-1259008
Journal	Synlett
Issue Number	18
Volume Number	2010
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2010-10-14
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Key Words Alkaloids Aza-morita-baylis-hillman reaction
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Synthesis of Onychine and Formal Synthesis of Eupolauridine via the Vinylogous Aza-Morita-Baylis-Hillman Reaction