NDLI: High-Pressure Au-Catalyzed Cycloisomerization of Internal 1,6- and 1,7-Enynes

Content Provider	Scilit
Author	Chaładaj, Wojciech Kocój, Małgorzata Jarosińska, Elżbieta
Copyright Year	2018
Description	Published as part of the Special Section $9^{th}$ EuCheMS Organic Division Young Investigator Workshop The influence of high pressure (in the kbar region) on the outcome of the Au(I)-catalyzed cycloisomerization of 1,6- and 1,7-enynes is presented. The positive effect of pressure is particularly marked for reactions involving sterically biased substrates (e.g. 1,6-enynes bearing atert-butyl substituent at the alkyne moiety) and the challenging cyclization of internal 1,7-enynes.
Related Links	http://pdfs.semanticscholar.org/cd1e/2dfc527886fc05ad77f6381e2c65773343ba.pdf http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1591756.pdf
Ending Page	1323
Page Count	5
Starting Page	1319
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0036-1591756
Journal	Synlett
Issue Number	10
Volume Number	29
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2018-02-02
Access Restriction	Open
Subject Keyword	Organic Chemistry Cycloisomerization Homogenous Catalysis
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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