NDLI: Claisen Rearrangements of Benzyl Vinyl Ethers and Heterobenzyl Vinyl Ethers

Content Provider	Scilit
Author	McGeary, Ross P. Burns, Jed M. Krenske, Elizabeth H.
Copyright Year	2018
Description	The Claisen rearrangement of benzylic substrates (benzyl vinyl ethers) has received considerably less attention than its well-known aliphatic and normal aromatic variants. Here, we review the rearrangement of both benzylic and heterobenzylic substrates, with examples of the reaction’s use in the synthesis of natural products and drug-like molecules.1 Introduction2 Early Attempts at the Benzyl-Claisen Rearrangement3 Successful Benzylic Examples4 Heterobenzylic Examples5 Conclusion
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1589529.pdf
Ending Page	1772
Page Count	23
Starting Page	1750
ISSN	00397881
e-ISSN	1437210X
DOI	10.1055/s-0036-1589529
Journal	Synthesis
Issue Number	09
Volume Number	50
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2018-03-07
Access Restriction	Open
Subject Keyword	Journal: Synthesis Organic Chemistry Claisen Rearrangement Sigmatropic Rearrangement Alder-ene Reaction Benzyl Vinyl Ethers
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Claisen Rearrangements of Benzyl Vinyl Ethers and Heterobenzyl Vinyl Ethers