NDLI: Chiral Thioimidazoline Ligands for Palladium-Catalyzed Asymmetric Allylation

Content Provider	Scilit
Author	Morimoto, Toshiaki Tachibana, Keijiro Achiwa, Kazuo
Copyright Year	1997
Description	Chiral thioarylimidazolines 1,2 were prepared as a new class of SN-hybrid ligands. Asymmetric allylic substitution of 1,3-diphenyl-2-propenyl pivalate 11 with dimethyl malonate in the presence of BSA-LiOAc has been successfully carried out with a chiral catalyst of a thioimidazoline 1-palladium complex in high enantioselectivities of up to 96% ee.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-1997-5785.pdf
Ending Page	785
Page Count	3
Starting Page	783
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-1997-5785
Journal	Synlett
Issue Number	7
Volume Number	1997
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	1997-07-01
Access Restriction	Open
Subject Keyword	Organic Chemistry Chiral Imidazoline Palladium Catalyst Asymmetric Allylation Catalytic Asymmetric Allylation
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Chiral Thioimidazoline Ligands for Palladium-Catalyzed Asymmetric Allylation