NDLI: Synthesis of a Novel Unsymmetrical Bisoxazoline Ligand with sp² Bridging Carbon

Content Provider	Scilit
Author	Liese, Andreas Yuryev, Ruslan
Copyright Year	2009
Description	A novel unsymmetrical bisoxazoline ligand was synthesized in one step by the Knoevenagel condensation of aldehydes with a C$ _{2}$-symmetric indane-derived bisoxazoline having two acidic hydrogens connected to the bridging carbon. The electronic properties of incorporated bridge substituent due to π-π conjugation with oxazoline rings can affect the catalytic performance of the ligand in asymmetric syntheses, as was shown for the Henry reaction between benzaldehyde and nitromethane.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1217760.pdf
Ending Page	2592
Page Count	4
Starting Page	2589
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0029-1217760
Journal	Synlett
Issue Number	16
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-09-03
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Bisoxazoline Ligands Asymmetric Catalysis Transition-metal Complexes Henry Reaction
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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